Journal of Structural and Construction Engineering

Journal of Structural and Construction Engineering

Investigating the Effect of precursor and Activator on the Properties of Geopolymer

Document Type : Review

Author
Assistant professor, Department of Civil and Environment Engineering, AmirKabir University of Technology, Tehran, Iran
Abstract
Geopolymer concrete is recognized as a green and sustainable alternative to conventional concrete, capable of reducing the environmental impacts associated with cement production. This study investigates the effect of pozzolanic materials such as fly ash, slag, and metakaolin on the mechanical properties and durability of geopolymer concrete. The research also explores the impact of alkaline solutions like NaOH and KOH on the geopolymerization process and compressive strength of the concrete. The results showed that the use of fly ash and slag as pozzolanic materials in combination with alkaline solutions significantly improves the compressive strength, durability, and stability of geopolymer concrete under various environmental conditions. Furthermore, the use of geopolymer concrete notably reduces CO2 emissions and can be applied in civil defense projects. Ultimately, the findings of this research indicate that using geopolymers as a substitute for cement not only provides environmental benefits but also enhances the mechanical properties and durability of concrete. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .. .
Keywords

Subjects


[1] Bandar, D., Hassani, N., & Khodaparast, M. M. (1390). Geopolymer concrete and its applications. The First International Conference on Natrava Concretes, Drinking Water Storage Tanks, Rasht, Golestan Urban Water and Sewerage Company. in Persian
[2] Palomo, A., Grutzeck, M.W., & Blanco, M.T. (1999). Alkali-activated fly ashes: A cement for the future. Cement and Concrete Research, 29(8), 1323–1329.
[3] Naik, T. R., & Singh, S. S. (1995). Use of high-calcium fly ash in cement-based construction materials. Proceedings of the Fifth CANMET/ACI International Conference on Fly Ash, Silica Fume, Slag, and Natural Pozzolans in Concrete, Milwaukee, 1–44.
[4] CEEJ_Volume 50_Issue 4_Pages 673-684 (1). (2016). Cement and Concrete Engineering Journal, 50(4), 673–684. https://doi.org/10.22060/ceej.2016.695.
[5] Singh, N. B., & Middendorf, B. (2020). Geopolymers as an alternative to Portland cement: An overview. Construction and Building Materials, 237, 117455. https://doi.org/10.1016/j.conbuildmat.2019.117455.
[6] Cong, P., & Cheng, Y. (2021). Advances in geopolymer materials: A comprehensive review. Journal of Traffic and Transportation Engineering (English Edition), 8(3), 283–314. https://doi.org/10.1016/j.jtte.2021.03.004.
[7] Temuujin, J., van Riessen, A., & Mackenzie, K. (2010). Preparation and characterization of fly ash-based geopolymer mortars. Construction and Building Materials, 24, 1906–1910.
[8] Bentz, D. P., & Ferraris, C. F. (2010). Rheology and setting of high-volume fly ash mixtures. Cement and Concrete Composites, 32(4), 265–270. https://doi.org/10.1016/j.cemconcomp.2010.01.008.
[9] Komljenović, M., Baščarević, Z., & Bradić, V. (2010). Mechanical and microstructural properties of alkali-activated fly ash geopolymers. Journal of Hazardous Materials, 181(1–3), 35–42. https://doi.org/10.1016/j.jhazmat.2010.04.064.
[10] Amran, Y. H. M., Alyousef, R., Alabduljabbar, H., & El-Zeadani, M. (2020). Clean production and properties of geopolymer concrete: A review. Journal of Cleaner Production, 251, 119679. https://doi.org/10.1016/j.jclepro.2019.119679.
[11] Lemougna, P. N., MacKenzie, K. J. D., Jameson, G. N. L., Rahier, H., & Melo, U. F. C. (2013). The role of iron in the formation of inorganic polymers (geopolymers) from volcanic ash: A 57Fe Mössbauer spectroscopy study. Journal of Materials Science, 48, 5280–5286.
[12] Tosti, L., van Zomeren, A., Pels, J. R., et al. (2018). Technical and environmental performance of lower carbon footprint cement mortars containing biomass fly ash as a secondary cementitious material. Resources Conservation and Recycling, 134, 25–33.
[13] Raisi, E. M., Amiri, J. V., & Davoodi, M. R. (2018). Mechanical performance of self-compacting concrete
incorporating rice husk ash. Construction and Building Materials, 177, 148–157.
[14] Glukhovsky, V. D. (1959). Soil silicates. Gosstroyizdat, Kiev, 154p.
[15] Xu, H., Provis, J. L., van Deventer, J. S., & Krivenko, P. V. (2008). Characterization of aged slag concretes. ACI Materials Journal, 105(2), 131–139.
[16] Davidovits, J. (1994). Properties of geopolymer cements. In First International Conference on Alkaline Cements and Concretes, 1, 131–149.
[17] Bakharev, T., Sanjayan, J. G., & Cheng, Y. B. (1999). Alkali activation of Australian slag cements. Cement and Concrete Research, 29(1), 113–120.
[18] Wang, S. D., Scrivener, K. L., & Pratt, P. L. (1994). Factors affecting the strength of alkali-activated slag. Cement and Concrete Research, 24(6), 1033–1043.
[19] Krizan, D., & Zivanovic, B. (2002). Effects of dosage and modulus of water glass on early hydration of alkali–slag cements. Cement and Concrete Research, 32(8), 1181–1188.
[20] Ravikumar, D., & Neithalath, N. (2012). Effects of activator characteristics on the reaction product formation in slag binders activated using alkali silicate powder and NaOH. Cement and Concrete Composites, 34(7), 809–818.
[21] Arya, S., Niranjan, V., & Husk, R. (2017). Experimental investigation on strength and durability characteristics of multi-blended cement concrete. Vol. 6, 20–22.
[22] Wang, H., Li, H., & Yan, F. (2005). Synthesis and mechanical properties of metakaolinite-based geopolymer. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 268(1), 1–6.
[23] Isgor, O. B., & Razaqpur, A. G. (2004). Finite element modeling of coupled heat transfer, moisture transport and carbonation processes in concrete structures. Cement and Concrete Composites, 26(1), 57–73.
[24] Juenger, M. C. G., Winnefeld, F., Provis, J. L., & Ideker, J. H. (2011). Advances in alternative cementitious binders. Cement and Concrete Research, 41(12), 1232–1243. https://doi.org/10.1016/j.cemconres.2010.11.012.
[25] Krivenko, P. V. (1994). Alkaline cements. In Proceedings of the First International Conference on Alkaline Cements and Concretes, 1, 11–129.
[26] Palomo, A., Grutzeck, M.W., & Blanco, M.T. (1999). Alkali-activated fly ashes: A cement for the future. Cement and Concrete Research, 29, 1323–1329.
[27] Duxson, P., Fernández-Jiménez, A., Provis, J. L., Lukey, G. C., Palomo, A., & van Deventer, J. S. J. (2007). Geopolymer technology: The current state of the art. Journal of Materials Science, 42(9), 2917–2933. https://doi.org/10.1007/s10853-006-0637-z.
[28] Rashad, A. M. (2014). A comprehensive overview about the influence of different admixtures and additives on the properties of alkali-activated fly ash. Materials Design, 53, 1005–1025. https://doi.org/10.1016/j.matdes.2013.07.074.
[29] Temuujin, J., Rickard, W., Lee, M., & van Riessen, A. (2011). Preparation and thermal properties of fire-resistant metakaolin-based geopolymer-type coatings. Journal of Non-Crystalline Solids, 357(5), 1399–1404. https://doi.org/10.1016/j.jnoncrysol.2010.09.063.
[30] Palomo, A., Fernández-Jiménez, A., López Hombrados, C., & Lleyda, J.L. (2007). Railway sleepers made of alkali activated fly ash concrete. Revista Ingeniería, 22(2), 75–80.
[31] Naik, T. R. (2008). Sustainability of concrete construction. Practice Periodical on Structural Design and Construction, 13(2), 98–103.
[32] Hassani, N., & Khodaparast, M. M. (1390). Geopolymer concrete and its applications. The First International Conference on Natrava Concretes, Drinking Water Storage Tanks, Rasht, Golestan Urban Water and Sewerage Company. in Persian
[33] Tchakoute, H. K., & Ruscher, C. H. (2017). Mechanical and microstructural properties of metakaolin-based geopolymer cements from sodium waterglass and phosphoric acid solution as hardeners: A comparative study. Applied Clay Science, 140, 81–87.
[34] Kovtun, M., Kearsley, E. P., Shekhovtsova, J. (2015). Dry powder alkali-activated slag cements. Advances in Cement Research, 27(8), 447–456.
[35] Ma, C., Zhao, B., Guo, S. L., et al. (2019). Properties and characterization of green one-part geopolymer activated by composite activators. Journal of Cleaner Production, 220, 188–199.
[36] Velandia, D. F., Lynsdale, C. J., Provis, J. L., et al. (2016). Evaluation of activated high volume fly ash systems using Na2SO4, lime and quicklime in mortars with high loss on ignition fly ashes. Construction and Building Materials, 128, 248–255.
[37] Helmy, A. I. I. (2016). Intermittent curing of fly ash geopolymer mortar. Construction and Building Materials, 110, 54–64.
[38] Singh, B., Ishwarya, G., Gupta, M., & Bhattacharyya, S. K. (2015). Geopolymer concrete: A review of some recent developments. Construction and Building Materials, 85, 78–90. https://doi.org/10.1016/j.conbuildmat.2015.03.036.
[39] Askarian, M., Tao, Z., Adam, G., et al. (2018). Mechanical properties of ambient cured one-part hybrid OPC-geopolymer concrete. Construction and Building Materials, 186, 330–337.
[40] Alrefaei, Y., Wang, Y., & Dai, J. (2019). The effectiveness of different superplasticizers in ambient cured one-part alkali activated pastes. Cement and Concrete Composites, 97, 166–174. https://doi.org/10.1016/j.cemconcomp.2019.01.019.
[41] Dong, M. H., Elchalakani, M., & Karrech, A. (2020). Development of high strength one-part geopolymer mortar using sodium metasilicate. Construction and Building Materials, 236, 117611. https://doi.org/10.1016/j.conbuildmat.2019.117611.
[42] Havaei, G., & Mohseni, S. (2025). The Environmental Resistance of Low-Carbon Geopolymer Concret, A Review Article. Journal of Structural and Construction Engineering12(01), 5-29.
[43] Havaei, G. (2023). Numerical evaluation of seismically retrofitted bridge concrete column under extreme loading. Structural Concrete24(4), 5349-5369.
[44] Havaei, G. R., & Keramati, A. (2011). Experimental and numerical evaluation of the strength and ductility of regular and cross spirally circular reinforced concrete columns for tall buildings under eccentric loading. The Structural Design of Tall and Special Buildings20(2), 247-256.
[45] Havaei, G., & Bayat, E. (2017). The structural response and manner of progressive collapse in RC buildings under the blast and Provide approaches to retrofitting columns against blast. Journal of Structural and Construction Engineering4(1), 81-100.
[46] Havaei, G. (2016). Sensitivity based analyses by artificial earthquake by measuring structural accelerations for damage assessment. Journal of Structural and Construction Engineering2(4), 104-116.
[47] Havaei, G., & Zare, A. (2017). Numerical analysis of effective parameters in response of the nonlinear passive viscous systems. Journal of Structural and Construction Engineering4(Special Issue 1), 35-47.
[48] Havaei, G., & Mobedi, E. (2015). Effect of interaction and rocking motion on the earthquake response of buildings. Journal of Structural and Construction Engineering1(1), 39-49.
[49] Havaei, G., & Izadparast, S. M. (2021). Effect of soil block thickness modeling on soil-structure interaction in dynamic responses of 15-storey high-rise buildings. Journal of Structural and Construction Engineering8(10), 301-316.
[50] Hayati, Y., Eslami, A., & Havaei, G. (2024). Asymmetric 3D stress-and flux-induced wave propagation in transversely isotropic thermoelastic solids by using of analytical methods. Waves in Random and Complex Media34(5), 4868-4885.
[51] Hayati, Y., Havaei, G., & Eslami, A. (2021). 3D asymmetric dynamic Green’s functions of a thermoelastic transversely isotropic solid by a method of potentials. Journal of Thermal Stresses44(11), 1366-1388.
 
Volume 9, Issue 10 - Serial Number 63
January 2023
Pages 231-251

  • Receive Date 25 December 2021
  • Revise Date 04 April 2022
  • Accept Date 28 May 2022